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Oxidized forms of a tripyrrane: alpha-tripyrrinone, beta-tripyrrinone and a C-2 symmetric hexapyrrole

TitleOxidized forms of a tripyrrane: alpha-tripyrrinone, beta-tripyrrinone and a C-2 symmetric hexapyrrole
Publication TypeJournal Article
Year of Publication2009
AuthorsShin, JY, Hepperle, SS, Patrick, BO, Dolphin, D
JournalChemical Communications
Pagination2323-2325
Type of ArticleArticle
ISBN Number1359-7345
KeywordsSUBSTITUTED EXPANDED PORPHYRINS
Abstract

alpha- and beta-tripyrrinone isomers (3-6), and a C-2 symmetric hexapyrrole (7) were isolated from the oxidation of meso-perfluorophenyl tripyrrane 1 (and meso-2,6-dichlorophenyl tripyrrane 2) with DDQ under aerobic conditions, and the structure of 3 was determined by X-ray crystallographic analysis.

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