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THE QUANTITATION OF BUTYLTIN AND CYCLOHEXYLTIN COMPOUNDS IN THE MARINE-ENVIRONMENT OF BRITISH-COLUMBIA

TitleTHE QUANTITATION OF BUTYLTIN AND CYCLOHEXYLTIN COMPOUNDS IN THE MARINE-ENVIRONMENT OF BRITISH-COLUMBIA
Publication TypeJournal Article
Year of Publication1990
AuthorsCullen WR, Eigendorf GK, Nwata BU, Takatsu A
JournalApplied Organometallic Chemistry
Volume4
Pagination581-590
Date PublishedNov-Dec
Type of ArticleArticle
ISBN Number0268-2605
Accession Numberhttp://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1990EU19500001
KeywordsBUTYLTIN SPECIES, CYCLOHEXYLTIN SPECIES, CYHEXTIN, GC MS, HPLC AA, HPLC MS, LIQUID-CHROMATOGRAPHY, ORGANOTIN COMPOUNDS, OYSTERS, PLICTRAN, SAMPLES, SEAWATER, SPECIATION, SURFACE MICROLAYER, WATER
Abstract

A HPLC/GF AA procedure based on the use of C-18 columns is described for the quantitation of butyltin species in marine samples. When a mass spectrometer was used as detector (HPLC MS), evidence was obtained for the presence of other tin compounds in the samples. Extracts of samples were treated with CH3MgBr and examined by using GC MS; the presence of BU(n)SnMe4-n (n = 3-1, Bu = butyl) and Cy(n)SnMe4-n (n = 3, 2, Cy = cyclohexyl) was confirmed in the derivatized seawater, bivalve flesh, and bivalve shell samples. Quantitative data are given for butyl- and cyclohexyl-tin species in seawater and the surface microlayer, and oyster flesh.

URLhttp://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1990EU19500001
Alternate JournalAppl. Organomet. Chem.

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