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Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal structure and magnetic properties of a one-dimensional material exhibiting ferromagnetic ordering below 8 K
| Title | Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal structure and magnetic properties of a one-dimensional material exhibiting ferromagnetic ordering below 8 K |
| Publication Type | Journal Article |
| Year of Publication | 1999 |
| Authors | Rettig SJ, Sanchez V, Storr A, Thompson RC, Trotter J |
| Journal | Inorganic Chemistry |
| Volume | 38 |
| Pagination | 5920-+ |
| Date Published | Dec |
| Type of Article | Article |
| ISBN Number | 0020-1669 |
| Accession Number | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=000084245200045 |
| Keywords | 3,5-DIMETHYLPYRAZOLATE COMPLEXES, BR, CH3, LIGANDS, METAL PYRAZOLATE POLYMERS, METALLOCENES |
| Abstract | Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal Structure and Magnetic Properties of a One-Dimensional Material Exhibiting Ferromagnetic Ordering below 8 K. The title compound has a rodlike 1-D structure in which iron ions are double bridged by 1-methyl-2-thioimidazolate ligands and the metal chromophores alternate along the chain between FeS4 and FeN4. Antiferromagnetic intrachain coupling with spin canting generates residual spin on the chains that undergo long-range ferromagnetic order below 8 K. |
| URL | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=000084245200045 |
| Alternate Journal | Inorg. Chem. |
