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Fourier transform spectroscopy of torsionally excited C-13 methanol in the CO-stretching band
| Title | Fourier transform spectroscopy of torsionally excited C-13 methanol in the CO-stretching band |
| Publication Type | Journal Article |
| Year of Publication | 1996 |
| Authors | Lees RM, Mukhopadhyay I, Predoi A, Lewisbevan W, Johns JW |
| Journal | Journal of Chemical Physics |
| Volume | 105 |
| Pagination | 3406-3418 |
| Date Published | Sep |
| Type of Article | Article |
| ISBN Number | 0021-9606 |
| Accession Number | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1996VD76800007 |
| Keywords | (CH3OH)-C-13, ASSIGNMENTS, CH3OH, DOUBLE-RESONANCE, EMISSION, FIR LASER, HIGH-RESOLUTION SPECTROSCOPY, IDENTIFICATION, INFRARED-LASER LINES, SPECTRUM |
| Abstract | Torsionally excited n=1 and n=2 subbands of the CO-stretching fundamental have been assigned in the Fourier transform infrared spectrum of (CH3OH)-C-13 recorded at a resolution of 0.002 cm(-1). For the n=1 torsional state, subbands with K values up to 7 have been identified for A torsional symmetry and up to 5 for E symmetry. For n=2, four subbands have so far been assigned. Subband origins have been obtained by fitting the observed wave numbers to J(J+-1) power-series expansions. The expansion parameters represent the data compactly to close to the experimental uncertainty in the absence of line blending or perturbations. Significant downshifting of the n=1 origins is observed, correlated closely with proximity to the n=0 OH-bending state. J-localized perturbations have been observed and characterized for several subbands. Two of the far-infrared laser lines optically pumped by the 10R(14) CO2 laser line have been assigned. (C) 1996 American Institute of Physics. |
| URL | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1996VD76800007 |
| Alternate Journal | J. Chem. Phys. |
