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Fourier transform spectroscopy of torsionally excited C-13 methanol in the CO-stretching band

TitleFourier transform spectroscopy of torsionally excited C-13 methanol in the CO-stretching band
Publication TypeJournal Article
Year of Publication1996
AuthorsLees RM, Mukhopadhyay I, Predoi A, Lewisbevan W, Johns JW
JournalJournal of Chemical Physics
Volume105
Pagination3406-3418
Date PublishedSep
Type of ArticleArticle
ISBN Number0021-9606
Accession Numberhttp://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1996VD76800007
Keywords(CH3OH)-C-13, ASSIGNMENTS, CH3OH, DOUBLE-RESONANCE, EMISSION, FIR LASER, HIGH-RESOLUTION SPECTROSCOPY, IDENTIFICATION, INFRARED-LASER LINES, SPECTRUM
Abstract

Torsionally excited n=1 and n=2 subbands of the CO-stretching fundamental have been assigned in the Fourier transform infrared spectrum of (CH3OH)-C-13 recorded at a resolution of 0.002 cm(-1). For the n=1 torsional state, subbands with K values up to 7 have been identified for A torsional symmetry and up to 5 for E symmetry. For n=2, four subbands have so far been assigned. Subband origins have been obtained by fitting the observed wave numbers to J(J+-1) power-series expansions. The expansion parameters represent the data compactly to close to the experimental uncertainty in the absence of line blending or perturbations. Significant downshifting of the n=1 origins is observed, correlated closely with proximity to the n=0 OH-bending state. J-localized perturbations have been observed and characterized for several subbands. Two of the far-infrared laser lines optically pumped by the 10R(14) CO2 laser line have been assigned. (C) 1996 American Institute of Physics.

URLhttp://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1996VD76800007
Alternate JournalJ. Chem. Phys.

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