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ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY
| Title | ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY |
| Publication Type | Journal Article |
| Year of Publication | 1994 |
| Authors | Turner NJ, Martel AA, Waller IM |
| Journal | Journal of Physical Chemistry |
| Volume | 98 |
| Pagination | 474-477 |
| Date Published | Jan |
| Type of Article | Article |
| ISBN Number | 0022-3654 |
| Accession Number | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1994MR53500021 |
| Keywords | CARBONYLS, COMPLEXES, FLIGHT MASS-SPECTROMETER, IDENTIFICATION, LASER, METAL-HYDRIDES, PHENYLNITRENE, photoelectron, SPECTRA, THRESHOLD PHOTODETACHMENT SPECTROSCOPY, TRANSITION-STATE |
| Abstract | In this work, we present the fixed-frequency (at 355 nm) negative-ion photoelectron spectrum of Co(CO)(2)NO-. Analysis of the spectrum yields the electron affinity of Co(CO)(2)NO; EA[Co(CO)(2)NO] = 1.73 +/- 0.03 eV. The lack of extensive vibrational progressions in the spectrum is consistent with the neutral species and the negative-ion having similar equilibrium geometries. |
| URL | http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=A1994MR53500021 |
| Alternate Journal | J. Phys. Chem. |
