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MOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OF THE STRUCTURALLY CHARACTERIZED DICHLORO(O-DIPHENYLPHOSPHINO-N,N-DIMETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE ]RUTHENIUM(II) COMPLEX

TitleMOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OF THE STRUCTURALLY CHARACTERIZED DICHLORO(O-DIPHENYLPHOSPHINO-N,N-DIMETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE ]RUTHENIUM(II) COMPLEX
Publication TypeJournal Article
Year of Publication1993
AuthorsMudalige, DC, Rettig, SJ, James, BR, Cullen, WR
JournalJournal of the Chemical Society-Chemical Communications
Pagination830-832
Date PublishedMay
Type of ArticleArticle
ISBN Number0022-4936
KeywordsDIHYDROGEN, LIGANDS, ruthenium
Abstract

The crystallographically characterised, five-coordinate complex [RuCl2(o-diphenylphosphino-N,N-dimethylaniline){P(p-tolyl)3}] reversibly binds H-2 and N2 to form eta2-H-2 and sigma-N2 species, respectively; the former reacts with base to generate the chloro(hydrido) derivative.

URL<Go to ISI>://A1993LD66800010