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MICHAEL-TYPE ADDITION OF 1,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE TO DIMETHYL ACETYLENEDICARBOXYLATE

TitleMICHAEL-TYPE ADDITION OF 1,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE TO DIMETHYL ACETYLENEDICARBOXYLATE
Publication TypeJournal Article
Year of Publication1995
AuthorsMa, LF, Dolphin, D
JournalJournal of the Chemical Society-Chemical Communications
Pagination2251-2252
Date PublishedNov
Type of ArticleArticle
ISBN Number0022-4936
KeywordsDBU
Abstract

Michael reaction of DBU 1 with dimethyl acetylenedicarboxylate 2 and subsequent intramolecular condensation of the adduct gives a tricyclic derivative 6; a mechanism for the formation of 6 is proposed and an X-ray crystal structure of 6: is presented.

URL<Go to ISI>://A1995TF60500002