|Title||Linearly conjugated benzocyclohexadienone photochemistry in the solid state: ionic chiral auxiliary mediated asymmetric induction|
|Publication Type||Journal Article|
|Year of Publication||1999|
|Authors||Cheung, E, Netherton, MR, Scheffer, JR, Trotter, J|
|Type of Article||Article|
|Keywords||ASYMMETRIC INDUCTION, KETONES, PHOTOCHEMISTRY, REARRANGEMENT, [pi(a)(2)+sigma(a)(2)]|
Asymmetric induction in the photochemistry of a linearly conjugated benzocyclohexadienone derivative has been achieved for the first time through the use of the solid state ionic chiral auxiliary method. Enantiomeric excesses as high as 70-80% at reasonable conversions are readily attainable. Crystal structures for both reactant and product are reported. (C) 1999 Elsevier Science Ltd. All rights reserved.
|URL||<Go to ISI>://000083827200005|