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AN ENANTIOSPECIFIC ROUTE TO C,D RING SYNTHONS FOR STEROID-SYNTHESIS

TitleAN ENANTIOSPECIFIC ROUTE TO C,D RING SYNTHONS FOR STEROID-SYNTHESIS
Publication TypeJournal Article
Year of Publication1992
AuthorsClase, JA, Money, T
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination1537-1544
Date PublishedMay
Type of ArticleArticle
ISBN Number0008-4042
KeywordsAPPROACH, asymmetric, CONSTRUCTION, Diels-Alder, ENANTIOSELECTIVE SYNTHESIS, GAMMA-BUTYROLACTONE DERIVATIVES, INHOFFEN-LYTHGOE DIOL, SIDE-CHAIN CONSTRUCTION, STEREOCONTROLLED, STEREOSELECTIVE SYNTHESIS, TANDEM ALKYLATION, TRIPLY CONVERGENT SYNTHESIS, VITAMIN-D METABOLITES
Abstract

A simple enantiospecific route to a hydrindenone intermediate for steroid synthesis has been accomplished. The introduction of a wide variety of side-chain units is made possible hy stereoselective alkylation of a bicyclic ester 13 derived from (+)-camphor 4.

URL<Go to ISI>://A1992JL87000031