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C(sp2)-C(sp2) cross coupling reactions catalyzed by an active and highly stable magnetically separable Pd-nanocatalyst in aqueous media

TitleC(sp2)-C(sp2) cross coupling reactions catalyzed by an active and highly stable magnetically separable Pd-nanocatalyst in aqueous media
Publication TypeJournal Article
Year of Publication2014
AuthorsZolfigol, MAli, Azadbakht, T, Khakyzadeh, V, Nejatyami, R, Perrin, DM
JournalRSC Adv.
Volume4
Pagination40036-40042
Abstract

A new magnetite Pd-nanoparticle supported (4{,}5-diazafluoren-9-one)-derived palladium chloride (7) was synthesized{,} characterized and introduced. The nanocatalyst exhibited an efficient activity in Suzuki cross-coupling reactions with an environmentally-friendly (H2O/DMF) solvent system for 1-3 h at 100 [degree]C and Mizoroki-Heck cross-coupling reactions. The catalyst can easily be recovered from the reaction system by using an external magnet and reused several times with high yields.

URLhttp://dx.doi.org/10.1039/C4RA06097K
DOI10.1039/C4RA06097K