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List of Publications

Thomas JM, Yoon JK, Perrin DM. Investigation of the Catalytic Mechanism of a Synthetic DNAzyme with Protein-like Functionality: An RNaseA Mimic? J Am Chem Soc. 2009;131:5648-58. Abstract
Thomas JM, Perrin DM. Probing General Acid Catalysis in the Hammerhead Ribozyme. J Am Chem Soc. 2009;131:1135-43. Abstract
Thomas JM, Perrin DM. Probing General Base Catalysis in the Hammerhead Ribozyme. J Am Chem Soc. 2008;130:15467-75. Abstract
Ting R, Thomas JM, Perrin DM. Kinetic characterization of a cis- and trans-acting M2+-independent DNAzyme that depends on synthetic RNaseA-like functionality - Burst-phase kinetics from the coalescence of two active DNAzyme folds. Canadian Journal of Chemistry-Revue Canadienne De Chimie. 2007;85:313-29. Abstract
Thomas JM, Perrin DM. Active site labeling of G8 in the hairpin ribozyme: Implications for structure and mechanism. Journal of the American Chemical Society. 2006;128:16540-5. Abstract
Ting R, Thomas JM, Lermer L, Perrin DM. Substrate specificity and kinetic framework of a DNAzyme with an expanded chemical repertoire: a putative RNaseA mimic that catalyzes RNA hydrolysis independent of a divalent metal cation. Nucleic Acids Res. 2004;32:6660-72. Abstract
Thomas JM, Walker NR, Cooke SA, Gerry MC. Microwave spectra and structures of KrAuF, KrAgF, and KrAgBr; Kr-83 nuclear quadrupole coupling and the nature of noble gas-noble metal halide bonding. J Am Chem Soc. 2004;126:1235-46. Abstract
Thomas JM, Ting R, Perrin DM. High affinity DNAzyme-based ligands for transition metal cations - a prototype sensor for Hg2+. Org Biomol Chem. 2004;2:307-12. Abstract
May JP, Ting R, Lermer L, Thomas JM, Roupioz Y, Perrin DM. Covalent Schiff base catalysis and turnover by a DNAzyme: A M2+ independent AP-endonuclease mimic. J Am Chem Soc. 2004;126:4145-56. Abstract

Recently Added

Ross A, Soares DC, Covelli D, Pannecouque C, Budd L, Collins A, et al. Oxovanadium(IV) cyclam and bicyclam complexes: potential CXCR4 receptor antagonists. Inorg Chem. 2010;49(3):1122-32. Abstract
Delgado-Jaime MU, Mewis CP, Kennepohl P. Blueprint XAS: a Matlab-based toolbox for the fitting and analysis of XAS spectra. J Synchrotron Radiat. 2010;17(1):132-7. Abstract
Bates JI, Kennepohl P, Gates DP. Abnormal reactivity of an N-heterocyclic carbene (NHC) with a phosphaalkene: a route to a 4-phosphino-substituted NHC. Angew Chem Int Ed Engl. 2009;48(52):9844-7.
Sriskandakumar T, Petzold H, Bruijnincx PC, Habtemariam A, Sadler PJ, Kennepohl P. Influence of oxygenation on the reactivity of ruthenium-thiolato bonds in arene anticancer complexes: insights from XAS and DFT. J Am Chem Soc. 2009;131(37):13355-61. Abstract
Kennepohl P, Wasinger EC, DeBeer George S. X-ray spectroscopic approaches to the investigation and characterization of photochemical processes. J Synchrotron Radiat. 2009;16(Pt 4):484-8. Abstract
Karunakaran-Datt A, Kennepohl P. Redox photochemistry of methionine by sulfur K-edge X-ray absorption spectroscopy: potential implications for cataract formation. J Am Chem Soc. 2009;131(10):3577-82. Abstract
Martin-Diaconescu V, Kennepohl P. Effects of hyperconjugation on the electronic structure and photoreactivity of organic sulfonyl chlorides. Inorg Chem. 2009;48(3):1038-44. Abstract
Praetorius JM, Allen DP, Wang R, Webb JD, Grein F, Kennepohl P, et al. N-heterocyclic carbene complexes of Rh: reaction with dioxygen without oxidation. J Am Chem Soc. 2008;130(12):3724-5. Abstract
Getty K, Delgado-Jaime MU, Kennepohl P. Assignment of Pre-edge Features in the Ru K-edge X-ray Absorption Spectra of Organometallic Ruthenium Complexes. Inorganica Chim Acta. 2008;361(4):1059. Abstract
Getty K, Delgado-Jaime MU, Kennepohl P. An electronic rationale for observed initiation rates in ruthenium-mediated olefin metathesis: charge donation in phosphine and N-heterocyclic carbene ligands. J Am Chem Soc. 2007;129(51):15774-6. Abstract

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